Sarah Michelle Gellar and Freddie Prinze Jr.

Sarah Michelle Gellar as Daphne and Freddie Prinze Jr. as Fred in Scooby-Doo (2002)

This pair met on the set of the 1997 teen horror film I Know What You Did Last Summer. They didn’t start dating until 2000 but quickly got engaged in 2001 and married in 2002. The year they married, they starred together again in Scooby-Doo, in which Gellar played Daphne and Prinze played, of course, Fred. Matthew Lillard played Shaggy and Linda Cardellini played Velma, with other castmates including Sugar Ray singer Mark McGrath, Rowan Atkinson, and Isla Fisher. Prinze Jr. and Gellar have two children: Charlotte and Rocky.

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