Spider-Man 2 (2004)
Peter Parker (Tobey Maguire) learns that with great power comes not just great responsibility, but great sacrifice, as he realizes that his role as Spider-Man endangers the love of his life, Mary Jane Watson (Kirsten Dunst). Doc Ock (Alfred Molina) is one of the all-time best spider villains, and the highlight of the whole film comes in a truly marvelous sequence in which New York City saves Spidey, for a change. The most romantic of all superhero movies, except for the last one on our list.
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